Abstract:Under the dual background of global value chain restructuring and "dual carbon" goal constraints, the impact and mechanism of digital service trade liberalization on the greening of corporate supply chains are explored, which is of great significance for achieving high-quality economic development. Based on the data of Chinese listed companies from 2014 to 2023, a multi-dimensional digital service trade liberalization index was constructed by integrating the OECD Digital Service Trade Restrictiveness Index with national input-output tables. The greening level of corporate supply chains was measured from three dimensions: environment, operations, and economic performance, and the internal correlation between the two was empirically tested. It was found that digital service trade liberalization significantly improves the greening level of corporate supply chains. This conclusion remains robust after processing with entropy balance matching and the instrumental variable method. Mechanism analysis shows that the green supply chain ecosystem is reshaped by digital service trade liberalization mainly through three paths: digital governance, supply chain resource allocation optimization, and international expansion. Heterogeneity analysis indicates that this effect is more prominent in growth-stage enterprises, those with strong green transformation intentions, and samples where executives have overseas backgrounds. At the industry level, higher sensitivity is observed in digital economy and high-tech industries. At the regional level, the promotional effect shows a significant dependence on the development level of the service industry and digital infrastructure. Further research finds that digital service trade liberalization not only promotes green transformation but also significantly enhances the resilience and security of the supply chain through the greening path. New micro-evidence is provided in this study regarding measurement methods, and policy enlightenment is offered for understanding how digital openness synergistically promotes "greenness" and "security" in supply chains.